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Its high U but low common Pb contents make it an ideal mineral for U–Pb isotopic dating of Nb–Ta mineralization.

In order to establish a feasible coltan dating method by in situ laser-ablation (LA) ICP–MS, we determined the U–Pb ages of five coltan samples from different pegmatites and rare-metal granites in China.

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In order to evaluate the potential matrix effect between different minerals, a 91500 zircon was used as external standard during analyses.

The results show that, compared to the recommended ages, approximately 7–15% younger ages were yielded for the analyzed coltan samples in both single spot and line raster scan analytical methods, indicating a significant matrix effect between coltan and zircon.

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Although the analyzed coltan minerals show a large variation of chemical compositions, no significant matrix effect was observed, which suggests that a coltan material should be used as an external standard for U–Pb dating of coltan by LA–ICP–MS.

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